Lithium makes more sense when weight is an issue, for example when you have to carry the battery around. Sodium batteries could be good for grid storage if they can be implemented as scale cheaply enough, especially using common materials.
Comment on The first EV with a lithium-free sodium battery hits the road in January
Newtra@pawb.social 6 months ago
This is awesome news. Not because of the car, but because it builds the supply lines for an alternative battery chemistry.
People have been using lithium-ion batteries for home and grid storage, which is nuts if you compare it to other battery types. Lithium is expensive and polluting and only makes sense if you’re limited by weight & space. Cheaper batteries, even if they’re bigger/heavier, will do wonders to the economics of sustainable electricity production.
profdc9@lemmy.world 6 months ago
sugar_in_your_tea@sh.itjust.works 6 months ago
A quick wikipedia read implies that sodium-ion batteries could be half or less the cost vs lithium. Also this:
Another factor is that cobalt, copper and nickel are not required for many types of sodium-ion batteries, and more abundant iron-based materials work well in Na+ batteries.
That’s probably most of why it’s cheaper, and it’s also way less damaging to the environment if they truly can be made from mostly sodium and iron.
I’m more concerned about the safety aspects. It seems there are two main types:
- aqueous - quite safe, but also likely very heavy per unit of energy
- carbon - high risk (probably similar to lithium)
That’s a big reason why I and probably many others aren’t interested in the current batch of EVs. Yeah they’re pretty safe, but they’re quite violent when they fail. I’d probably buy a sodium-ion EV if it could get 100-150 miles range reliably. That would be absolutely sufficient for my commute, even in the winter, and it would make a fantastic “around town” car when I’m not working.
wikibot@lemmy.world [bot] 6 months ago
Here’s the summary for the wikipedia article you mentioned in your comment:
Sodium-ion batteries (NIBs, SIBs, or Na-ion batteries) are several types of rechargeable batteries, which use sodium ions (Na+) as its charge carriers. In some cases, its working principle and cell construction are similar to those of lithium-ion battery (LIB) types, but it replaces lithium with sodium as the cathode material. Sodium belongs to the same group in the periodic table as lithium and thus has similar chemical properties. In other cases (such as aqueous Na-ion batteries) they are quite different from Li-ion batteries. SIBs received academic and commercial interest in the 2010s and early 2020s, largely due to the uneven geographic distribution, high environmental impact, and high cost of lithium. An obvious advantage of sodium is its natural abundance, particularly in saltwater. Another factor is that cobalt, copper and nickel are not required for many types of sodium-ion batteries, and more abundant iron-based materials work well in Na+ batteries. This is because the ionic radius of Na+ (116 pm) is substantially larger than that of Fe2+ and Fe3+ (69–92 pm depending on the spin state), whereas the ionic radius of Li+ is similar (90 pm). Similar ionic radii of lithium and iron result in their mixing in the cathode material during battery cycling, and a resultant loss of cyclable charge. A downside of the larger ionic radius of Na+ is a slower intercalation kinetics of sodium-ion electrode materials.The development of Na+ batteries started in the 1990s. After three decades of development, NIBs are at a critical moment of commercialization. Several companies such as HiNa and CATL in China, Faradion in the United Kingdom, Tiamat in France, Northvolt in Sweden, and Natron Energy in the US, are close to achieving the commercialization of NIBs, with the aim of employing sodium layered transition metal oxides (NaxTMO2), Prussian white (a Prussian blue analogue) or vanadium phosphate as cathode materials.Electric vehicles using sodium-ion battery packs are not yet commercially available. However, CATL, the world’s biggest lithium-ion battery manufacturer, announced in 2022 the start of mass production of SIBs. In February 2023, the Chinese HiNA Battery Technology Company, Ltd. placed a 140 Wh/kg sodium-ion battery in an electric test car for the first time, and energy storage manufacturer Pylontech obtained the first sodium-ion battery certificate from TÜV Rheinland.
quo@feddit.uk 6 months ago
[deleted]bstix@feddit.dk 6 months ago
Used car batteries can be reused for storage, so it’s going to require a cost analysis to determine what makes most sense for storage solutions. It’s great if they can use a cheaper sodium battery but we also don’t want to just waste the second hand lithium batteries. It makes sense to use both. At least until there are better recycling options. Also with solid state batteries hopefully coming up soon, it’ll still make sense to find use for the current batteries.
Ideally, home backups should be able to use any battery. Standards for compatibility would be nice.
___@lemm.ee 6 months ago
Not just that, we don’t have enough lithium deposits atm to build enough lithium evs to last more than a few decades if we act smart (which we generally do not).
PraiseTheSoup@lemm.ee 6 months ago
Cheaper batteries, even if they’re bigger/heavier
Yes, just what we need is more vehicles on the road that weigh as much as a tank but accelerate like a Ferrari. I’m sure that won’t cause any problems.
You999@sh.itjust.works 6 months ago
Compared to other battery chemistry types using lithium makes tons of sense.
Lead acid type batteries like sealed and AGM are cheap but not power dense and do not offer the same discharge ability that lithium offers without damaging the battery (AGM fixes this but it’s still an issue). Some lead acid batteries require continuous maintenance and vent toxic gasses which may be an issue depending on your encloser.
Nickel cadmium batteries solve a lot of issues that lead acid batteries are plagued with however they suffer from moisture intrusion issues causing self discharge. Nickel cadmium also suffers from memory effect which may completely ruin pour battery depending on your use. The elephant in the room with nickel cadmium is that it’s banned in some countries including the European union due to how toxic cadmium is.
Now with lithium, it’s a very energy dense battery which means you need less batteries to meet a capacity or you can fit more capacity into an encloser. There isn’t any electrolyte or water maintenance you need to worry about. You can discharge and recharge as you wish with minimal damage. Really the only downsides is that they do not like charging in the cold, are just as toxic as cadmium, and are much much much more expensive.
theblueredditrefugee@lemmy.dbzer0.com 6 months ago
I find it interesting that, on a post about sodium ion batteries, your comment completely excludes them
You999@sh.itjust.works 6 months ago
The original comment was about lithium and their popularity for backup power. Sodium ion batteries are so new that you can’t purchase them yet (blueitte supposedly released the NA300 but I can’t find any in stock and it’s no longer on their site).
It wouldn’t be fair to compare a chemistry you cannot purchase and which it’s strengths and weaknesses haven’t been tested outside of controlled laboratory testing.
theblueredditrefugee@lemmy.dbzer0.com 6 months ago
Fair point - I’m not really that good with the physical sciences personally so apologies for my ignorance
astral_avocado@lemm.ee 6 months ago
You can buy them right now, there’s more links in the 18650masterrace subreddit, but here’s just one:
srikobatteries.com/…/sodium-ion-18650-1250mah-50a…
However good luck finding a BMS that works for it’s particular voltage range, don’t think AliExpress has any yet.
ShepherdPie@midwest.social 6 months ago
Probably because they’re new and the parent comment specifically referred to the cheaper, less energy dense battery types.
Newtra@pawb.social 6 months ago
I agree that older commercialized battery types aren’t so interesting, but my point was about all the battery types that haven’t had enough R&D yet to be commercially mass-produced.
Power grids don’t care much about density - they can build batteries where land is cheap, and for fire control they need to artificially space out higher-density batteries anyway. There are heaps of known chemistries that might be cheaper per unit stored (molten salt batteries, flow batteries, and solid state batteries based on cheaper metals), but many only make sense for energy grid applications because they’re too big/heavy for anything portable.
I’m saying it’s nuts that lithium ion is being used for cases where energy density isn’t important. It’s a bit like using bottled water on a farm because you don’t want to pay to get the nearby river water tested. It’s great that sodium ion could bring new economics to grid energy storage, but weird that the reason it was developed is for consumer applications.
greenmarty@lemmy.world 6 months ago
and explosive
zalgotext@sh.itjust.works 6 months ago
Seems like some pretty big and numerous downsides lmao
InformalTrifle@lemmy.world 6 months ago
*enclosure
AlexisFR@jlai.lu 6 months ago
Don’t forget the volatility of Lithium batteries if they ever get damaged or punctured.
absentbird@lemm.ee 6 months ago
What about nickle-metal hydride?