Tangentially Speaking by Chris Ryan.

He interviews interesting people, some famous, most not. The latest episode was with a guy he happened to meet at a party and thought he had an interesting story.

As the name implies he is very happy to go off on tangents, so the episodes can end up in topics you never would have guessed from the guest description.

Word of warning he does tend to talk for about 30 minutes at the start of every episode. I personally enjoy it but I know others who it annoys.