From your description, this sounds a lot like how double/triple pane windows work, or like a Trombe wall. Although a Trombe wall is meant to heat a home, vents could be used to take advantage of convection currents that shed the heat away from the house.

That said, this wouldn’t necessarily be cooling per-se, but would be avoiding heat gain. And at that point, any material that’s loosely coupled to then house would be equally effective, like a wall with studs 24" (60 cm) apart rather than the USA standard of 16" (40 cm).