Tp calculate needs way more info that. U would need to know the effective efficiency of the central heating system. The houses per room insulation effect and inter room insulating effect. The heat output of each device. Ambient temperature. Then u could do some thermodynamic analysis to determine which is more expensive. Alternatively u just measure both taking care to compare the getting to temp and maintaining temp separately.

I believe u thermostats are a standard wiring so u can probably wire up a relay and a raspberry pi with a wireless thermostat.